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刘仲杰, 崔育新*, 刘雪辉, 闵吉梅, 张礼和
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Liu Zhongjie, Cui Yuxin*, Liu Xuehui, Min Jimei, Zhang Lihe
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摘要: 利用Ferrier反应, 合成了一类新的含有二糖结构的核苷类似物。通过GCOSY和GNOESY技术归属了所有的质子, 并讨论了这类化合物的构型。所得结论与计算机分子模拟结果一致。
关键词: Ferrier反应, 核苷类似物, 1H NMR
Abstract: A new kind of nucleoside analogues containing disaccharide resulting from Ferrier reaction of glycal was synthesized. Their (a, b, c, d) 1H NMR signals were assigned by GCOSY and GNOESY, the configuration was also determined. The results are in accord with computer-aided molecular simulation.
Key words: Ferrier reaction, Ferrier reaction, Nucleoside analogues, Nucleoside analogues, 1H NMR, 1H NMR
Supporting:
刘仲杰, 崔育新*, 刘雪辉, 闵吉梅, 张礼和. 1H NMR研究含有二糖结构的核苷类似物构型[J]. .
Liu Zhongjie, Cui Yuxin*, Liu Xuehui, Min Jimei, Zhang Lihe. Study on the Configuration of Nucleoside Analogues Containing Disaccharide by 1H NMR[J]. .
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链接本文: http://jcps.bjmu.edu.cn/CN/
http://jcps.bjmu.edu.cn/CN/Y2000/V9/I1/19