Oxidative coupling of α–bromoarylacetonitriles and oxidative decyanation of diarylacetonitriles catalyzed by solid-liquid phase transfer

doi:10.5246/jcps.2012.05.054

Abstract

Abstract: Oxidative coupling of α-bromoarylacetonitriles and oxidative decyanation of diarylacetonitriles are efficiently realized by solid-liquid phase transfer catalysis using anhydrous K₃PO₄ as base and TBAB as catalyst in acetone at room temperature. In this mild and convenient method, α,β-dicyanostilbenes and diarylketones were prepared in good to excellent yields.

Key words: Solid-liquid phase transfer catalysis, Oxidative coupling reaction, α,β-Dicyanostilbenes, Oxidative decyanation, Diarylketones

CLC Number:

R916

Supporting:

Xin Zhang^¶, Xueling Hou^¶, Fangbin Han, Zemei Ge^*, Tieming Cheng, Runtao Li^*. Oxidative coupling of α–bromoarylacetonitriles and oxidative decyanation of diarylacetonitriles catalyzed by solid-liquid phase transfer[J]. , DOI: 10.5246/jcps.2012.05.054.

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